UNCOVERING THE ROLE OF CERIUM-CONTAINING COMPOUNDS IN PLASMA SYNTHESIS OF LUMINESCENT MATERIALS

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Abstract

Luminescent materials based on Al5O6N doped with Ce3+ ions were prepared via plasma-chemical process resulting from a microwave discharge initiated in metal-dielectric powder mixtures. The subthreshold self-non-self-sustained discharge was initiated by microwave pulses with a frequency of 75 GHz, a power of 400 kW, and a duration of 8 ms in Al/γ-Al2O3/melamine mixtures. Cerium was introduced in the forms of CeO2 and Ce(acac)3H2O, as well as via pre-doping of γ-Al2O3 with Ce3+ ions. The kinetic parameters of the plasma-chemical process were determined. The products of the process were studied with electronic microscopy and X-ray diffraction analysis, also their pulsed cathodoluminescence spectra were measured. It has been shown that the rate of the plasma-chemical process and the efficiency of the Ce3+ ions incorporation into the resulting phase of aluminum oxynitride Al5O6N strongly depend on the nature of cerium-containing precursor.

About the authors

N. S. Akhmadullina

Institute of Metallurgy and Materials Science named after. A.A. Baikov Russian Academy of Sciences

Email: nakhmadullina@mail.ru
Moscow, Russia

A. K. Kozak

Institute of General Physics named after A.M. Prokhorov Russian Academy of Sciences

Moscow, Russia

A. E. Petrov

Institute of General Physics named after A.M. Prokhorov Russian Academy of Sciences

Moscow, Russia

D. O. Pozdnyakov

Institute of General Physics named after A.M. Prokhorov Russian Academy of Sciences

Moscow, Russia

I. Yu. Vafin

Institute of General Physics named after A.M. Prokhorov Russian Academy of Sciences

Moscow, Russia

A. S. Sokolov

Institute of General Physics named after A.M. Prokhorov Russian Academy of Sciences

Moscow, Russia

O. N. Shishilov

Institute of General Physics named after A.M. Prokhorov Russian Academy of Sciences; MIREA - Russian Technological University

Email: oshishilov@gmail.com
Moscow, Russia; Moscow, Russia

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