METAL COMPLEX CHROMOPHORES BASED ON o-IMINOBENZOQUINONATO DERIVATIVES OF COBALT(III), COPPER(II) AND NICKEL(II): MOLECULAR STRUCTURE, ELECTRONIC ABSORPTION SPECTRA AND THERMAL PROPERTIES

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

A series of the 3d-row transition metal complexes was synthesized on the base of o-aminophenol АРН2N2Ph augmented by azo-fragment: bis-o-iminobenzosemiquinonate derivatives (imSQN2Ph)2Ni (1), (imSQN2Ph)2Cu (2), as well as mixed-ligand compound (imSQN2Ph)(APN2Ph)Co (3) (where imSQN2Ph and APN2Ph are radical anion and dianion redox-forms of ligand АРН2N2Ph, correspondingly). The molecular structure of ligand АРН2N2Ph and complexes 1·C7H8, 2·C7H8 and 3·C7H8 was determined using x-ray diffraction analysis (CIF files CCDC Nos 2444549-2444553, correspondingly). The planar coordination environment of metal center caused the mutual planar displacement of frontier orbitals HOMO and LUMO, that is why low-energy charge transfer "ligand-to-ligand" is implemented in compounds 1-3, corresponding the light absorption in the IR-region. Obtained metal complexes are characterized by rich set of redox states, predominantly provided by redox-active nature of ligands. The compounds of nickel(II) 1 and cobalt(III) 3 are volatile and distinguished by high thermostability and completeness transfer into the vapor phase, that is the favourable factor for the design of optoelectronic devices based on them using the vacuum deposition method.

Авторлар туралы

K. Pashanova

G.A. Razuvaev Institute of Organometallic Chemistry

Email: pashanova@iomc.ras.ru
Nizhny Novgorod, Russia

N. Lazarev

G.A. Razuvaev Institute of Organometallic Chemistry

Nizhny Novgorod, Russia

I. Yakushev

N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Moscow, Russia

A. Zolotukhin

G.A. Razuvaev Institute of Organometallic Chemistry

Nizhny Novgorod, Russia

T. Kovylina

G.A. Razuvaev Institute of Organometallic Chemistry

Nizhny Novgorod, Russia

M. Arsenyev

G.A. Razuvaev Institute of Organometallic Chemistry

Nizhny Novgorod, Russia

A. Bogomyakov

International Tomography Centre Siberian Branch of Russian Academy of Sciences

Novosibirsk, Russia

A. Maximova

National Research Centre "Kurchatov Institute"

Moscow, Russia

P. Dorovatovskii

National Research Centre "Kurchatov Institute"

Moscow, Russia

A. Piskunov

G.A. Razuvaev Institute of Organometallic Chemistry

Moscow, Russia

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