Determination of kinetic parameters of the methane pyrolysis process on a NiO-CuO-Al2O3 catalyst using mathematical modeling methods

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Abstract

Kinetic parameters for methane pyrolysis on a NiO-CuO-Al2O3 catalyst were obtained using mathematical modeling methods. The pre-exponential factor and activation energy were determined for two kinetic models, with the calculated values adequately describing the experimental points. The mathematical model was verified. Using a system of equations that takes into account catalyst deactivation over time and numerical calculations, the kinetic parameters of the deactivation process were determined: activation energy Ed = 95 kJ/mol and k0d values for different deactivation order d. It was shown that in mathematical modeling of the catalytic pyrolysis of methane on a NiO-CuO-Al2O3 catalyst, the root-mean-square relative error values do not exceed 2.5–7.9% in the high-temperature range of 625–650°C, which makes it possible to use both kinetic models for numerical calculations.

About the authors

E. V Shelepova

Boreskov Institute of Catalysis SB RAS

Email: shev@catalysis.ru
Novosibirsk, Russia

D. M Shivtsov

Boreskov Institute of Catalysis SB RAS

Novosibirsk, Russia

S. D Afonnikova

Boreskov Institute of Catalysis SB RAS

Novosibirsk, Russia

G. B Veselov

Boreskov Institute of Catalysis SB RAS

Novosibirsk, Russia

Yu. I Bauman

Boreskov Institute of Catalysis SB RAS

Novosibirsk, Russia

I. V Mishakov

Boreskov Institute of Catalysis SB RAS

Novosibirsk, Russia

A. A Vedyagin

Boreskov Institute of Catalysis SB RAS

Novosibirsk, Russia

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