Effect of Pretreatment with Phosphoric Acid on the Catalytic Properties of Pd/C Obtained by the Pyrolytic Method in the Hydrodechlorination of Chlorobenzene

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Abstract

Pd/C catalysts containing reduced palladium nanoparticles on activated carbon were obtained by pyrolysis of wood sawdust impregnated sequentially or simultaneously with phosphoric acid and palladium nitrate. Low-temperature nitrogen adsorption-desorption, scanning electron microscopy, X-ray photoelectron spectroscopy and Raman spectroscopy methods show that pyrolysis leads to the formation of microporous carbon material with high content of graphite-like carbon and high specific surface area (1600-1900 m2/g) regardless of the acid treatment conditions. According to X-ray photoelectron spectroscopy and transmission electron microscopy, the obtained Pd/C catalysts include predominantly nanosize Pd particles. Co-impregnation with phosphoric acid and palladium nitrate provides catalyst with larger average palladium particle size, higher surface palladium content and increased activity and stability in gas-phase hydrodechlorination of chlorobenzene in comparison to catalyst obtained by sequential impregnation with phosphoric acid and palladium nitrate and characterized by slightly higher fraction of reduced palladium.

About the authors

S. V Klokov

Lomonosov Moscow State University, Chemistry Department

Email: servadklokov@gmail.com
ORCID iD: 0000-0001-9913-8496
Moscow, Russia

E. S Lokteva

Lomonosov Moscow State University, Chemistry Department

ORCID iD: 0000-0003-3510-4822
Moscow, Russia

E. V Golubina

Lomonosov Moscow State University, Chemistry Department

ORCID iD: 0000-0002-1040-1428
Moscow, Russia

M. M Kasyanov

Lomonosov Moscow State University, Chemistry Department

Moscow, Russia

K. I Maslakov

Lomonosov Moscow State University, Chemistry Department

ORCID iD: 0000-0002-0672-2683
Moscow, Russia

O. Ya Isaykina

Lomonosov Moscow State University, Chemistry Department

ORCID iD: 0000-0002-4165-6562
Moscow, Russia

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