Vinylation of Arythiols with Calcium Carbide

封面

如何引用文章

全文:

开放存取 开放存取
受限制的访问 ##reader.subscriptionAccessGranted##
受限制的访问 订阅存取

详细

The corresponding vinyl thioethers were synthesized by the interaction of calcium carbide with 4-tert-butylbenzylthiol, 4-methoxybenzylthiol, and 1,4-mercaptobenzene in yields up to 92%. The reaction proceeds well both in the presence of bases and in the presence of basic salts alone. The resulting vinyl thioethers can be used to synthesize polymers with desired properties.

作者简介

M. Savitsky

Saint Petersburg State University

St. Petersburg, Russia

Yu. Gyrdymova

Saint Petersburg State University

Email: y.gyrdymova@spbu.ru
ORCID iD: 0000-0002-4592-822X
St. Petersburg, Russia

参考

  1. Li P., Tu C., Xun M.-M., Wu W.-X. Eur. Polym. J. 2022, 177, 111482. https://doi.org/10.1016/j.eurpolymj.2022.111482
  2. Ziegenbalg N., Gruschwitz F.V., Adermann T., Mayr L., Guriyanova S., Brendel J.C. Polym. Chem. 2022, 13, 4934–4943. https://doi.org/10.1039/D2PY00598K
  3. Mondal K., Patra S., Halder P., Mukhopadhyay N., Das P. Org. Lett. 2023, 25, 1235. https://doi.org/10.1021/acs.orglett.2c03856
  4. Bosch M., Schlaf M. J. Org. Chem. 2003, 68, 5225. https://doi.org/10.1021/jo034376h
  5. Spiegelberg B., Jiao H., Grauke R., Kubis C., Spannenberg A., Brandt A., Taden A., Beck H., Tin S., de Vries J.G. Adv. Synth. Catal. 2022, 364, 1251. https://doi.org/10.1002/adsc.202101348
  6. Alavez-Rosas D., Maldonado-Dominguez M., Gonzalez-Antonio O., Romero-Avila M., Mendez-Stivalet J., Flores-Perez B. Chem. Heterocycl. Compd. 2017, 53, 526. https://doi.org/10.1007/s10593-017-2087-8
  7. Гырдымова Ю.В., Потороченко А.Н. Изв. АН, сер. хим. 2025, 74 (6), 1–16.
  8. Zhang Z., Wen F., Liu H., Li Z. ChemistrySelect. 2022, 7, e202201463. https://doi.org/10.1002/slct.202201463
  9. Wang Y., Wen F., Li Z. Chem. Asian J. 2022, 17, e202200698. https://doi.org/10.1002/asia.202200698
  10. Jing T., Liu N., Xu C., Bu Q. Eur. J. Org. Chem. 2022, 2022, e202200178. https://doi.org/10.1002/ejoc.202200178
  11. Gyrdymova Yu.V., Zarubina S.M., Rodygin K.S. Mendeleev Commun. 2024, 34 (5), 732–733. https://doi.org/10.1016/j.mencom.2024.09.034
  12. Gyrdymova Y.V., Samoylenko D.E., Rodygin K.S. Chem. Asian J. 2023, 18, e202201063. https://doi.org/10.1002/asia.202201063
  13. Gyrdymova Yu.V., Saybulina E.R., Mironenko R.M., Rodygin K.S. Asian J. Org. Chem. 2024, 13, e202400147. https://doi.org/10.1002/ajoc.202400147
  14. Ma X., Li Z. Synlett. 2021, 32, 631. https://doi.org/10.1055/s-0040-1706638
  15. Lotsman K.A., Rodygin K.S. Green Chem. 2023, 25, 3524. https://doi.org/10.1039/D2GC04932E
  16. Lotsman K.A., Rodygin K.S., Skvortsova I., Kutskaya A.M., Minyaev M.E., Ananikov V.P. Org. Chem. Front. 2023, 10, 1022–1033. https://doi.org/10.1039/D2QO01652D
  17. Rodygin K.S., Gyrdymova Y.V., Ananikov V.P. Russ. Chem. Rev. 2022, 91, RCR5048. https://doi.org/10.1070/RCR5048
  18. Gyrdymova Yu.V., Lebedev A.N., Du Y.-J., Rodygin K.S. ChemPlusChem. 2024, 89 (11), e202400247. https://doi.org/10.1002/cplu.202400247
  19. Rodygin K.S., Ananikov V.P. Green Chem. 2016, 18, 482–486. https://doi.org/10.1039/C5GC01552A
  20. Werner G., Rodygin K.S., Kostin A.A., Gordeev E.G., Kashin A.S., Ananikov V.P. Green Chem. 2017, 19, 3032–3041. https://doi.org/10.1039/C7GC00724H

补充文件

附件文件
动作
1. JATS XML
下载

版权所有 © Russian Academy of Sciences, 2025

Согласие на обработку персональных данных

 

Используя сайт https://journals.rcsi.science, я (далее – «Пользователь» или «Субъект персональных данных») даю согласие на обработку персональных данных на этом сайте (текст Согласия) и на обработку персональных данных с помощью сервиса «Яндекс.Метрика» (текст Согласия).