Мақаланы E-mail арқылы жіберу Reorganization energies of methylamine radicals
- Авторлар: Miroshnichenko E.A.1, Kon’kova Т.S.1, Matyushin Y.N.1, Vorob’ev A.B.1, Inozemtsev J.O.1, Inozemtsev A.V.1
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Мекемелер:
- N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
- Шығарылым: Том 15, № 3 (2022)
- Беттер: 117-120
- Бөлім: Articles
- URL: https://medbiosci.ru/2305-9117/article/view/286677
- DOI: https://doi.org/10.30826/CE22150312
- EDN: https://elibrary.ru/KUBXFX
- ID: 286677
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Аннотация
To calculate the energy of the reorganization of methylamine radicals, the enthalpy of formation in the gas phase of the corresponding compounds and the enthalpies of formation of amine radicals have been used. The specifics of these compounds lies in the fact that each radical can be investigated through hydrogen derivatives and through methyl derivatives, i. e., to determine the reorganization energies of radicals through independent enthalpies of the formation of composition in the gas phase and to determine the average values. The obtained values made it possible to determine the dissociation energies and the average thermochemical bond energies (C–H and C–N) in methylamines derivatives.
Авторлар туралы
Eugeny Miroshnichenko
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Хат алмасуға жауапты Автор.
Email: eamir02@mail.ru
Doctor of Science in chemistry, chief research scientist
Ресей, MoscowТatiana Kon’kova
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: taskon@mail.ru
Doctor of Science in chemistry, chief research scientist
Ресей, MoscowYury Matyushin
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: ynm07@mail.ru
Doctor of Science in technology, head of laboratory
Ресей, MoscowAlexey Vorob’ev
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: ynm07@mail.ru
Candidate of Science in technology, senior research scientist
Ресей, MoscowJaroslav Inozemtsev
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: vectr1@yandex.ru
senior research scientist
Ресей, MoscowAlexey Inozemtsev
N. N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences
Email: vectr1@yandex.ru
research scientist
Ресей, MoscowӘдебиет тізімі
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