LOW-TEMPERATURE SYNTHESIS OF SnO NANOSHEETS VIA CHEMICAL DEPOSITION: MORPHOLOGY, STRUCTURE, AND THERMAL STABILITY

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

The formation process of SnO nanosheets was studied using the direct chemical precipitation, employing tin(II) chloride as the tin source and sodium hydroxide as the base. The obtained powder was characterized in terms of its crystalline structure and microstructure using X-ray diffraction (XRD), scanning electron microscopy (SEM), and atomic force microscopy (AFM). Spectral characteristics were examined by infrared (IR) and Raman spectroscopy, and thermal behavior was analyzed using simultaneous thermal analysis (TGA/DSC) in an air flow. It was established that the synthesized SnO is resistant to oxidation at temperatures up to 250°C. According to XRD data, the product formed has a tetragonal crystal lattice corresponding to tin monoxide, with an average coherent scattering region (CSR) size of 21.7 ± 1.3 nm. SEM and AFM analyses revealed that the powder possesses a hierarchically organized microstructure consisting of nanoplates with a thickness of 26.2 ± 2 nm and lateral dimensions ranging from 0.6 to 4.3 μm. The work function of the material's surface was estimated using Kelvin probe force microscopy (KPFM) and found to be 3.79 ± 0.02 eV.

Авторлар туралы

I. Solomatov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; National Research University "Higher School of Economics"

Email: ivsolomatov@yandex.ru
Moscow, Russia

N. Fisenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

N. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

Ph. Gorobtsov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

T. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

E. Simonenko

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Moscow, Russia

Әдебиет тізімі

  1. Sivaramasubramaniam R., Muhamad M.R., Radhakrishna S. // Phys. Status Solidi A. 1993. V. 136. № 1. P. 215. https://doi.org/10.1002/pssa.2211360126
  2. Ogo Y., Hiramatsu H., Nomura K. et al. // Appl. Phys. Lett. 2008. V. 93. № 3. P. 1. https://doi.org/10.1063/1.2964197
  3. Pan X.Q., Fu L. // J. Electroceram. 2001. V. 7. № 1. P. 35. https://doi.org/10.1023/A:1012270927642
  4. Guo W., Fu L., Zhang Y. et al. // Appl. Phys. Lett. 2010. V. 96. № 4. P. 1. https://doi.org/10.1063/1.3277153
  5. Liang L.Y., Liu Z.M., Cao H.T. et al. // ACS Appl. Mater. Interfaces. 2010. V. 2. N. 4. P. 1060. https://doi.org/10.1021/am900838z
  6. Tsukazaki A., Ohtomo A., Onuma T. et al. // Nat. Mater. 2005. V. 4. N. 1. P. 42. https://doi.org/10.1038/nmat1284
  7. Kawazoe H., Yasukawa M., Hyodo H. et al. // Nature. 1997. V. 389. N. 6654. P. 939. https://doi.org/10.1038/40087
  8. Simonenko E.P., Nagornov I.A., Mokrushin A.S. et al. // Micromachines (Basel). 2023. V. 14. N. 4. P. 725. https://doi.org/10.3390/mi14040725
  9. Bazito F.F.C., Torresi R.M. // J. Braz. Chem. Soc. 2006. V. 17. N. 4. P. 627. https://doi.org/10.1590/S0103-50532006000400002
  10. Luo H., Liang L.Y., Cao H.T. et al. // ACS Appl. Mater. Interfaces. 2012. V. 4. N. 10. P. 5673. https://doi.org/10.1021/am301601s
  11. Чжоу Д., Чеканников А.А., Семененко Д.А. и др. // Журн. неорган. химии. 2022. Т. 67. № 9. С. 1350. https://doi.org/10.31857/S0044457X22090021
  12. Wang L., Ji H., Zhu F. et al. // Nanoscale. 2013. V. 5. N. 16. P. 7613. https://doi.org/10.1039/c3nr00951c
  13. Iqbal M.Z., Wang F., Hussain R. et al. // Mater. Focus. 2014. V. 3. N. 2. P. 92. https://doi.org/10.1166/mat.2014.1147
  14. Pan X.Q., Fu L. // J. Appl. Phys. 2001. V. 89. N. 11. P. 6048. https://doi.org/10.1063/1.1368865
  15. Fan H., Reid S.A. // Chem. Mater. 2003. V. 15. N. 2. P. 564. https://doi.org/10.1021/cm0208509
  16. Forster M. // Energy. 2004. V. 29. N. 5-6. P. 789. https://doi.org/10.1016/S0360-5442(03)00185-3
  17. Soares M.R., Dionisio P.H., Baumvol I.J.R. et al. // Thin Solid Films. 1992. V. 214. N. 1. P. 6. https://doi.org/10.1016/0040-6090(92)90449-L
  18. Васильев А.А., Лагутин А.С., Набиев Ш.Ш. // Журн. неорган. химии. 2020. Т. 65. № 12. С. 1710. https://doi.org/10.31857/S0044457X20120193
  19. Zhu L., Yang H., Jin D. et al. // Inorg. Mater. 2007. V. 43. N. 12. P. 1307. https://doi.org/10.1134/S0020168507120102
  20. Sun G., Qi F., Li Y. et al. // Mater. Lett. 2014. V. 118. P. 69. https://doi.org/10.1016/j.matlet.2013.12.048
  21. Kumar B., Lee D.-H., Kim S.-H. et al. // J. Phys. Chem. C. 2010. V. 114. N. 25. P. 11050. https://doi.org/10.1021/jp101682v
  22. Hill M.S., Johnson A.L., Lowe J.P. et al. // Dalton Trans. 2016. V. 45. N. 45. P. 18252. https://doi.org/10.1039/C6DT02508K
  23. Wu D.-S., Han C.-Y., Wang S.-Y. et al. // Mater. Lett. 2002. V. 53. N. 3. P. 155. https://doi.org/10.1016/S0167-577X(01)00468-2
  24. Krishnakumar T., Pinna N., Kumari K.P. et al. // Mater. Lett. 2008. V. 62. N. 19. P. 3437. https://doi.org/10.1016/j.matlet.2008.02.062
  25. Moreno M.S., Mercader R.C., Bibiloni A.G. // J. Phys.: Condens. Matter. 1992. V. 4. N. 2. P. 351. https://doi.org/10.1088/0953-8984/4/2/004
  26. Xu X., Ge M., Stahl K. et al. // Chem. Phys. Lett. 2009. V. 482. N. 4-6. P. 287. https://doi.org/10.1016/j.cplett.2009.10.012
  27. Aliahmad M., Dehbashi M. // Iran. J. Energy Environment. 2013. V. 4. N. 1. P. 49. https://doi.org/10.5829/idosi.ijee.2013.04.01.08
  28. Liang Y., Zheng H., Fang B. // Mater. Lett. 2013. V. 108. P. 235. https://doi.org/10.1016/j.matlet.2013.07.016
  29. Wang S., Xie S., Li H. et al. // Chem. Commun. 2005. N. 4. P. 507. https://doi.org/10.1039/b414913k
  30. Dai Z.R., Pan Z.W., Wang Z.L. // Adv. Funct. Mater. 2003. V. 13. N. 1. P. 9. https://doi.org/10.1002/adfm.200390013
  31. Iqbal M.Z., Wang F., Javed Q. et al. // Mater. Lett. 2012. V. 75. P. 236. https://doi.org/10.1016/j.matlet.2012.01.126
  32. Uchiyama H., Imai H. // Cryst. Growth Des. 2007. V. 7. N. 5. P. 841. https://doi.org/10.1021/cg070205k
  33. Jia Z., Zhu L., Liao G. et al. // Solid State Commun. 2004. V. 132. N. 2. P. 79. https://doi.org/10.1016/j.ssc.2004.07.028
  34. Iqbal M.Z., Wang F., Rafi-ud-Din et al. // Mater. Lett. 2012. V. 78. P. 50. https://doi.org/10.1016/j.matlet.2012.03.056
  35. Orlandi M.O., Leite E.R., Aguiar R. et al. // J. Phys. Chem. B. 2006. V. 110. N. 13. P. 6621. https://doi.org/10.1021/jp057099m
  36. Sun Z., Liao T., Dou Y. et al. // Nat. Commun. 2014. V. 5. N. 1. P. 3813. https://doi.org/10.1038/ncomms4813
  37. Timmerman M.A., Xia R., Le P.T.P. et al. // Chem. - A Eur. J. 2020. V. 26. N. 42. P. 9084. https://doi.org/10.1002/chem.201905735
  38. Deng D., Novoselov K.S., Fu Q. et al. // Nat. Nanotechnol. 2016. V. 11. N. 3. P. 218. https://doi.org/10.1038/nnano.2015.340
  39. Stoller M.D., Park S., Zhu Y. et al. // Nano Lett. 2008. V. 8. N. 10. P. 3498. https://doi.org/10.1021/nl802558y
  40. Osada M., Sasaki T. // Adv. Mater. 2012. V. 24. N. 2. P. 210. https://doi.org/10.1002/adma.201103241
  41. ten Elshof J.E., Yuan H., Gonzalez Rodriguez P. // Adv. Energy Mater. 2016. V. 6. N. 23. P. 1600355. https://doi.org/10.1002/aenm.201600355
  42. Liu Y., Yamaguchi A., Yang Y. et al. // Angew. Chem. Int. Ed. 2023. V. 62. N. 17. P. e202300640. https://doi.org/10.1002/anie.202300640
  43. Phuong P.H., Hoa H.T.M., Hung N.H. et al. // ChemistrySelect. 2021. V. 6. N. 43. P. 12246. https://doi.org/10.1002/slct.20210281750
  44. Zhu Y., Yang L., Guo S. et al. // Materials. 2023. V. 16. N. 2. P. 792. https://doi.org/10.3390/ma16020792
  45. Janardhan E., Reddy M.M., Reddy P.V. et al. // World J. Nano Sci. Eng. 2018. V. 08. N. 02. P. 33. https://doi.org/10.4236/wjnse.2018.82002
  46. Sangaletti L., Depero L.E., Allieri B. et al. // J. Mater. Res. 1998. V. 13. N: 9. P. 2457. https://doi.org/10.1557/JMR.1998.0343
  47. Liu Q., Liang L., Cao H. et al. // J. Mater. Chem. C: Mater. 2015. V. 3. N: 5. P. 1077. https://doi.org/10.1039/C4TC02184C
  48. Wang X., Zhang F.X., Loa I. et al. // Phys. Status Solidi B. 2004. V. 241. N: 14. P. 3168. https://doi.org/10.1002/pssb.200405231
  49. Giefers H., Porsch F., Wortmann G. // Physica B: Condens Matter. 2006. V. 373. N: 1. P. 76. https://doi.org/10.1016/j.physb.2005.10.136
  50. Gao Y., Zhao X., Yin P. et al. // Sci Rep. 2016. V. 6. N: 1. P. 20539. https://doi.org/10.1038/srep20539
  51. Kuang X., Liu T., Wang W. et al. // Appl. Surf. Sci. 2015. V. 351. P. 1087. https://doi.org/10.1016/j.apsusc.2015.04.190
  52. Talebian N., Jafarinezhad F. // Ceram Int. 2013. V. 39. N: 7. P. 8311. https://doi.org/10.1016/j.ceramint.2013.03.101
  53. Haspulat B., Saribel M., Kamış H. // Arab. J. Chem. 2020. V. 13. N: 1. P. 96. https://doi.org/10.1016/j.arabjc.2017.02.004
  54. Li X., Liang L., Cao H. et al. // Appl. Phys. Lett. 2015. V. 106. N: 13. P. 132102. https://doi.org/10.1063/1.4916664
  55. Kripalani D.R., Sun P.-P., Lin P. et al. // Appl. Surf. Sci. 2021. V. 538. P. 147988. https://doi.org/10.1016/j.apsusc.2020.147988

Қосымша файлдар

Қосымша файлдар
Әрекет
1. JATS XML
Жүктеу

© Russian Academy of Sciences, 2025

Согласие на обработку персональных данных

 

Используя сайт https://journals.rcsi.science, я (далее – «Пользователь» или «Субъект персональных данных») даю согласие на обработку персональных данных на этом сайте (текст Согласия) и на обработку персональных данных с помощью сервиса «Яндекс.Метрика» (текст Согласия).